Heat oven to 350°F (177°C). Line the bottom of an 8-inch round cake pan with parchment and lightly grease the sides.
In a heat-safe bowl, melt the butter and 3/4 cup dark chocolate chips until smooth.
Stir in sugar, oil, vanilla, and eggs until glossy and well combined.
Sift or whisk in cocoa powder, flour, and baking powder. Mix just until no dry streaks remain.
Dissolve coffee granules in hot water, then pour into the batter. Stir until smooth.
Pour batter into the prepared pan and bake 30–40 minutes, until the center is set and a toothpick comes out with moist crumbs.
Cool 10–15 minutes in the pan, then turn out and cool completely.
For ganache, heat heavy cream until steaming. Pour over 1 1/2 cups dark chocolate chips, let sit 2 minutes, then stir until smooth.
Let ganache cool until thick and spreadable, stirring occasionally.
Spread ganache over the cooled cake and create swirls. Chill briefly for cleaner slices if desired.